Thanks Yip, I knew how to do it and stuff, just don't know if there are any holy grail values, that's all.
Well I found that in portraits, too much blue will make you look like a zombie, and I have found ambiguous but good results having more red or greens. So yeah...
http://www.deviantart.com/deviation/48154831/ It's myself and quite a few curves were done on it, but the main thing is that in the normal greyscale conversion, my lips were lighter than when I did the channel mixing conversion.
Also it's suppose to be fun so I use curves and levels like 4 or 5 times.