Mikhail,
Good question.
Under normal circumstances there's a fixed relationship between the factors that vary the exposure on an image that you're going to make. For instance, 1/125 @ f8 is the same as 1/60 @ f/11 or 1/250 @ f5.6. Each of these values will yield the same amont of light for the creation of your image.
When you bring film into the equation, and start using longer or shoter exposure times, this relationship begins to break down, and where you might normally expect the same relationships to apply (1 second @ 5.6 = 2 seconds @ f 8 = 4 seconds @ f 11) what actually occurs is that the image on the film, at, say, that four second exposure, might appear to be underexposed, and in order to yield a correctly exposed image, you may need to compensate by increasing the exposure to perhaps six or eight seconds.
Here's a couple of references to this that I found after a quick google.
http://www.nyip.com/tips/tip_reciprocity698.html
http://medfmt.8k.com/mf/reciprocity.html
Hopefully others will be able to add more to this.