I don't have one of these, but I do have access to one and have played with it a bit.
Be aware that out towards the edge of the image circle (which you approach when you start shifting) this lens has fairly severe chromatic aberrations (colour fringing). The newer (Mk.II) lens improves this, but even it's not perfect.
Usually when I have CA in a shot I just tweak the adjustments in ACR/Lightroom. However as soon as you shift or tilt, the CA corrections available in RAW processors are no use. They assume that the lens is centred on the sensor.
What you need to do is stitch the images together with no CA correction, THEN use Photoshop's Lens Corrections filter to reduce the CA. On normal shots it doesn't do as a good a job as the corrections in ACR, but in this case it will do a better job.
I usually use Photoshop's inbuilt PhotoMerge function to merge multiple images (typically 3-5 shots, depending on whether the camera is horizontal/vertical, full-frame/1.6x, etc). Or you could make a large canvas, put each image on a layer, and move them around by hand. PhotoMerge is quicker and easier.
Then flatten, then correct CA, then correct any distortion/tilt issues, then crop back to a rectangle in your desired aspect ratio.
For "shift panoramas" to work properly, you really need the lens to remain in the same place and the camera body to move behind it. That way you get no parallax/etc issues between the photos.
However this is slightly awkward with the TS-E lenses. Some other shift adapters actually have a tripod mount under the lens which makes this easy, but what you'll have to do is shift the lens in one direction, then shift the camera back the same amount in the opposite direction so the lens is back where it started.
On my gear (which uses Arca-Swiss style QR plates) I just loosen the clamp, slide the camera, and retighten the clamp. It's not too hard, but depending on your gear this might be very awkward. You might be interested in reading
this article at Digital Outback Photo.
One other thing: the Mk.I lens by default has the tilt and shift functions acting at 90 degrees to each other. It is possible to reconfigure the lens so that they're in the same axis. It just takes a screwdriver (although you need to be careful to not damage the internal cables when putting the rear plate back on the lens). There are several tutorials on the web showing how to do this.