Steffan,
What you say is sort of fine, as long as the vehicles are stationary. Kyle has stated that he wants this for motorsport, where the cars are expected to be mobile.
The reduction effect of the reflectance, off glass, water, paint, whatever, is always dependant upon the alignment of the angles through which the rays of light are travelling.
A polariser is directional, and cancels out some of those directional rays, and you basically adjust the filter to achieve the maximum amount of cancellation, thus improving the relative transmission of the remainder of the light.
As the cars are going to be mobile, and it's the reflection of the light from the sun that you will typically be trying to address, the relative angles between the sun, vehicles, and yourself will always be changing, and thus the effectiveness of the polariser will be rendered to be of variable effect, often to a point of being totally useless, unless you can adjust the polariser while you're following the cars.
Not something I would suggest as being being easy to do, especially when trying to simply follow focus.
Steffen wrote:The polariser's dependance on the angle of sunlight is only for reducing atmospheric dispersion,
Actually, I don't accept this particular point. Were this the case, then there would be zero effect when you are using a polariser to see "through" a reflection off, say, a glass windscreen or window into the interior of a building or vehicle.
But we know that by simply rotating the polariser we can dial in the effect of the polariser by cancelling out light rays that travel in just the one particular direction. With a stationary car windshield less than, say, two meters away, this is a most effective technique, and there is unlikely to be very much atmospheric dispersion involved over that short a distance.
But that isn't the scenario that Kyle is thinking about.